Chapter 5. Periodic Classification of Elements

History of Periodic Table

* Dobereiner’s law of triads: In a triad, the atomic mass of the middle element is equal
to the arithmetic mean of the atomic masses of the other two.
* Newlands law of octaves: When elements are arranged in increasing order of their atomic weights, the properties of the eighth element are a repetition of the properties of the first element.
* Mendeleev’s law: The physical and chemical properties of elements are a periodic function of their atomic weights.

Modern Periodic Table


* Atomic number is the number of protons in an atom.

* The number of electrons in an atom is equal to the number of protons.
* An atom is electrically neutral.

* Valence electrons: Electrons in the shell of an atom.
* Electronic configuration: The arrangement of electrons in an atom around its nucleus.
* Bohr’s theory: Electrons are not located randomly around an atom’s nucleus, but occur in definite electron shells.

* The physical and chemical properties of elements are a periodic function of their atomic
numbers.
* Elements are arranged in the increasing order of atomic number.

The modern periodic table consists of:
*  7 horizontal periods
*  18 vertical groups

* The properties of the elements in the periodic table change gradually from left to right.

* Group I elements are called alkali metals.
* Group II elements are called alkaline earth metals.
* Group VII elements are called halogens.
* Zero group elements are referred to as inert gases.

Periodic Properties


* The properties of elements, which recur at regular intervals, are called periodic
properties.
* Atomic size increases in a group and decreases in a period.
* Ionization energy increases across a period and decreases down a group.
* Electron affinity increases across a period and decreases down a group.
* Electronegativity increases across a period and decreases down a group.
* Metallic character decreases across a period and increases down a group.
* Non-metallic character increases across a period and decreases down a group.

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