Chapter 3. Study of Acids, Bases and Salts

Acids, Bases and Salts – Acids

* Any substance that releases hydrogen ions when dissolved in water is an acid.

* Acids obtained from food like curd, lemons, raw mango, citrus fruits and gooseberry are called organic acids.
* Hydrochloric acid, sulphuric acid and nitric acid are called inorganic or mineral acids.

Acids have the following physical properties:

   *  Acids taste sour.
   *  Acids turn blue litmus red.
   *  Acids turn methyl orange red.
   *  Acids have a corrosive action on the skin.
   *  Acids are good conductors of electricity.
   *  Acids generate heat when they are diluted.

Acids have the following chemical properties:

   *  Acids react with metals to form metal salts.
   * Acids react with metal carbonates to form corresponding salts, carbon dioxide and water.
   *  Acids react with metal hydrogen carbonates and form corresponding salts, carbon dioxide and water.
   *  Acids react with metal oxide to form salt and water.

* Methyl orange turns red in an acid and yellow in a base.

* Phenolphthalein does not change colour in an acid. It turns pink in a base.
* Sulphuric acid is used in the manufacture of fertilisers, paints, dyes, chemicals, plastic, synthetic fibre and in car batteries.
* Nitric acid is used in the manufacture of fertilisers, explosives like TNT, dyes and drugs.

Hydrochloric acid is used:

   * Before galvanising, to remove oxide film from steel.
   *  As a descaling agent for boilers.
   *  In the textile, leather and food industry.

Acids and Bases and Salts- Strength of Acids and Bases


* A substance that produces hydroxide ions in water is known as a base.

Bases are:
   *  Bitter to taste
   *  Soapy to touch
   *  Change red litmus to blue

* Strong alkalis react with metals like zinc, aluminium etc. to liberate hydrogen.

* Salt and water are products, when bases react with non-metal oxides.
* Mild bases are used as antacids.
* A base like sodium hydroxide is used in the manufacturing of soaps, paper and synthetic fibre.
* Calcium hydroxide is used in manufacturing of bleaching powder.
* Bases are also used in the preparation of fertilisers like ammonium phosphate.
* Neutralisation is a chemical reaction in which an acid reacts with a base to form salt and water.
* An acid or base is strong or weak depending on the concentration of hydrogen and hydroxide ions.
* The concentration of hydrogen ion in acids and bases can be measured using the pH scale.

On the pH scale:

   *  A neutral solution has a pH value of 7
   *  A solution with a pH value of less than 7 is acidic
   *  A solution with a pH value of more than 7 is basic

Acids, Bases and Salts – Salts and their Properties


* A compound formed by the reaction between an acid and base is known as a
salt.
* Salts are solids and ionic compounds.
* Based on the strength of the reacting acid and base, salts are classified into neutral, acidic and basic salt.
* Sodium chloride is obtained from the sea and used to preserve pickles, to manufacture soaps, to melt ice and in the preparation of other compounds.
* Salts which have a fixed number of water molecules as an essential part of their crystal are called hydrate salts.
* Plaster of Paris is used as a bandage, proofing materials, and a sealing agent and for making statues, toys and decorative articles.

Acids and Bases: Ionisation and pH


* According to the Arrhenius theory, the strength of an acid and a base is
relating to the ease with which they function as a source of plus ions and minus ions in an aqueous medium.
* In terms of the Bronsted – Lowry theory, a strong acid readily donates the protons and a strong base readily accepts a proton.
* Strong acids have week conjugate bases and weak acids have strong conjugate bases.
* The ionic product of water, Kw, at a given temperature, id defined as the product of the concentrations of H plus and OH minus ions in water or in aqueous solutions.
* Aqueous solutions can be categorised as neutral solutions, acidic solutions and basic solution, depending upon the relative number of H plus and OH minus ions.
* The pH of a solution is defined as negative logarithm to the base 10 of the molar hydrogen concentration in it.
* Based on the value of the ionic product of water, the pH scale has values from 1 to 14. A solution with ph value seven is neutral, less than seven is acidic, and more than seven is basic.

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